LIMESTONE

About Limestone

Limestone is a kind of sedimentary rock composed mainly of calcium carbonate in the form of calcite minerals. (Sedimentation is the process of suspending particles getting settled down under the effect of gravity.)

The chief component of Limestone is Calcite, a calcium carbonate mineral. Apart from Calcite, Limestone contains other minerals, including Quartz, feldspar, pyrite, siderite, and clay minerals. Moreover, Limestone includes almost 10% of all rocks. Bedded type sedimentary Limestone is used in industries that require Limestone in bulk quantity. Moreover, 50% of Limestone is calcium carbonate. The types of Limestone differ and depend upon the formation, appearance, and composition.

Limestone Formation

According to geological perspective, Limestone forms in clear, warm, and shallow marine waters. The formation also takes place in water evaporating environments that result in cave formation.

The formation of Limestone is conventionally found in two different environments.

  • Biogenic precipitation from seawater: lime secreting organisms and foraminifera.
  • Deposition of preexisting Limestone: Travertine, tufa, caliche, chalk sparite, and micrite.

Organic Limestone

In the marine ecosystem, when fossils of the dead animals get accumulated as sediment, their shell and skeletal waste get accumulated as sediment and forms into Limestone.

Inorganic Limestone

Here, the formation of Limestone takes place by direct precipitation of calcium carbonate. When calcium carbonate gets precipitated directly from the solution, it forms as cement and binds the biological grains.

Cave Limestone

The formation of Limestone also takes place during evaporation. When water droplets seep down through the fractures and pores in the cave ceiling, the water evaporates, and the dissolved calcium carbonate deposits on it. Over time, this evaporation process leads to the formation of icicle-shaped Limestone.

LIMESTONE EXTRACTION PROCESS

Limestone is extracted by means of blasting or mechanical excavation.

The extracted ore is transported for the crushing process.

Once it is crushed, it will be stored in different fractions for screening.

The end product will be Limestone.

Forms Of Limestone

Chalk

Chalk is a fine-grained and light-colored Limestone formed by the sediments of skeletons of marine organisms. It is soft and can be cracked easily. Earlier, natural chalk was used to write on blackboards. But now, the chalk we use for blackboard is man-made, and some of it is made from natural chalk additives.

Coquina

Coquina is a poorly consolidated Limestone that is mainly composed of sand-size fragments of calcareous shell. A little calcareous cement binds the grains together so that they will be cemented poorly. It is ideal for home decoration.

Travertine

Travertine is a chemical formation of Limestone resulting from the evaporation on the roof of caves – stalactites.

Travertine can be recognized by its porous texture and low hardness (3Mohs) and was widely used in architecture.

Tufa

Tufa is a porous Limestone produced by the precipitation of calcium carbonate. It is a combination of biological and chemical processes that takes place near the waterfalls.

Fossiliferous Limestone

The main ingredient of fossiliferous Limestone is fossils. It can be further divided into microscopic and macroscopic fossiliferous stones. Macroscopic fossiliferous stones include Gastropods, brachiopods, crinoids, and hard-shelled mollusca. In contrast, the microscopic fossiliferous stones include diatoms and single-celled organisms.

Lithographic Limestone

It is a fine-grained and homogeneous rock that is so hard and impenetrable. In the early days of the printing industry, it was used for painting incredible images.

Oolitic Limestone

As the name signifies, the Oolitic Limestone resembles the shape of an egg. The granules imitate small eggs. The formation of Oolitic Limestone takes place due to the accumulation of calcium carbonate layers around sand grains. It is extensively used in construction industries.

Where Is It Found?

Limestone deposits can be found in the shallow waters in the Caribbean Sea, Indian Ocean, Persian Gulf, Gulf of Mexico, within the Indonesian archipelago, and around Pacific Ocean islands.

The abundance of corals, algae, mollusca, fishes, diatoms, and other calcium-rich marine organisms lead to the formation of Limestone.

The deposits of Limestone vary according to the place they occur. In lakes, the formation of Limestone can be referred to as stagnant deposits. In seas, it is referred to as deep-sea deposits. If Limestone is deposited in springs, rivers, or underground water, it is referred to as freshwater or streaming deposits. If it is deposited in meteoric caves, it is referred to as evaporative or vapor-based deposits.

Uses Of Limestone

Limestone is widely used in manufacturing Quicklime, slacked lime, portland cement, and mortar. Here are the applications of Limestone in various fields.

Applications Of Limestone

Travertine is widely in swimming pool construction. Its non-slip feature and heat resistance make it an ideal choice for coping and pool deck area building. As travertine is affordable when compared to other marbles, it is a good choice for pools.

For years, Limestone has been widely used to construct door sills, window sills, headers, and water tables.

Soil acidity can influence plant growth and can reduce crop production. When you spread agricultural lime onto the soil, acidic soil can be neutralized using the calcium components of Limestone's calcites. Thus, fragmented Limestone can be considered the best choice for conditioning soil. Limestone with 90% of calcium carbonate content can be used in the farming sector. It is crushed and differentiated into various grades according to its size and then used as agricultural limes.

In steel production, large amounts of Limestone and lime can be used to remove impurities during the iron ore reduction and steel production process.

Limestone's calcium oxide can act as a pH regulator while extracting gold from Quartz. While extracting gold from powdered Quartz, sodium cyanide solution is used. In this process, the pH level has to be maintained between 10-11 to prevent the production of deadly hydrogen cyanide gas. In that case, when you add calcium oxide to that solution, the pH can be maintained within the 10-11 range.

Limestone with calcium carbonate content above 95% can be considered high-grade Limestone. It is then quarried and crushed to different sizes. The crushed powder can be used as fillers in manufacturing paints, plastics, cleanser, paper, and carpets.

Limestone is cut into blocks of specific dimensions and used in the construction industries. It is used as facing stone, floor tiles, window sills, and stair treads.

General Requirements Of Limestone

The stone should not have any soft veins or cracks. Instead, it should be in uniform size and texture; its curvature should not exceed 5mm.

PROPERTIES OF LIMESTONE

Physical properties of Limestone slabs

Characteristics

Requirement

Method of Test (ref to Indian standard)

Water absorption

0.15 percent by weight

IS : 1124-1974*

Transverse strength

70 kg/cm2

IS : 1124-1974*

Durability

Shall not develop signs of spalling, disintegration of cracks

IS : 1124-1974*

SAMPLING

Standard sizes of Limestone Slabs and Tiles

Length

Breadth

Thickness

15 to 60 cm in stages of 5 cm

15 to 60 cm in

stages of 5 cm

15 to 95 mm in

stages of 10 mm

60 to 100 cm in

stages of 10 cm

30 to 100 cm in

stages of 10 cm

15 to 95 mm in

stages of 10 mm

100 to 150 cm in

stages of 10 cm

30 to 100 cm in

stages of 10 cm

25 to 95 mm in

stages of 10 mm

Sampling

The standards specified by the Indian Standards Institution have to be followed.

The number of slabs or tiles selected for the sample should conform to all the standards mentioned by the Indian Standards Institution. The samples are selected at random.

Marking

The lime package should be marked with its type, class, manufacturer's brand name, date of manufacturing the product, and net weight. For quicklime packages, the slaking temperature should be mentioned.

It is preferred to mark the lime packages with the standard mark.

The provisions of the Bureau of Indian Standards act, 1986 is governing the Standard Mark. The conditions which were granted to the manufacturers are obtained from the Indian Standards.

Those who manufacture Limestone slabs or tile should mark it with the manufacturer's identification mark or initials.

Packing

For supplying hydrated lime, proper containers should be used, such as polythene-lined jute bags or polythene-lined high-density polythene woven bags, or craft paper bags.

For supplying quick lime, metal containers can be used.

GRADES OF LIMESTONE

The composition of calcium carbonate and silica determines the quality/grade of Limestone. The more calcium carbonate, the better the quality. Based on this, we have three major grades of Limestone: Low Silica Limestone, Chemical Grade Limestone, and White Cement Grade Limestone.

Low Silica Limestone:

  • The composition of calcium carbonate in low silica limestone exceeds 95%. In comparison, silica accounts for less than 1.5%.
  • Low silica limestone plays a vital role in the steel industry. It is used as a flux in purifying steel in oxygen and electric arc furnaces.
  • When limestone is added to a mixture in steel making furnace, it reacts with impurities like silica, phosphorous, and sulfur and then forms a liquid slag. The impurities will then be separated from the steel and removed from the furnace.

Chemical Grade Limestone:

  • Chemical Grade Limestone, popularly referred to as ground calcium carbonate (GCC), is known for its physical and chemical consistency.
  • In Chemical Grade Limestone, calcium carbonate exceeds 94 %, and the presence of silica is lesser than 2.5%.
  • Chemical Grade Limestone plays a crucial role in the chemical industry in manufacturing quick lime and hydrated lime.
  • For desulfurization, Chemical Grade Limestone is widely used as a reagent.

White Cement Grade Limestone:

  • The presence of calcium carbonate in White Cement Grade Limestone (91%) is comparatively lesser than the low silica and chemical grade limestone.
  • The portion of the impurities exceeds 4% (silica < 4% and iron oxide 0.1%). However, the white cement grade Limestone is extensively used in cement and gray cement plants.
  • Cement Grade Limestone is the key ingredient in manufacturing cement.

Presence of Limestone in India- Reserves

The total reserves/resources of Limestone as per NMI (National Mineral Inventory) data is estimated to be 203,224 million tonnes.

16,336 million tonnes (8%) - reserves category

1,86,889 million tonnes (92%) - remaining resources category

State

Reserve

Karnataka

27%

Andhra Pradesh

12%

Rajasthan

12%

Gujarat

10%

Meghalaya

9%

Telangana

8%

Chattisgarh

5%

Madhya Pradesh

5%

Other states

12%

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